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September 1999
7100 9971 1308—SDTDC



Iron and Manganese In Drinking Water

Brenda Land, Senior Sanitary Engineer

Introduction
Iron and manganese (Fe/Mn) are common in groundwater supplies used by many Forest Service water systems. Iron is the more frequent of these two contaminants, but they often occur together. High levels of these contaminants can result in discolored water, stained plumbing fixtures, and an unpleasant metallic taste to the water. This can lead to employee and visitor complaints about the water. Iron deposits can buildup in pressure tanks, storage tanks, water heaters, and pipelines. Iron-deposit buildup can decrease capacity, reduce pressure, and increase maintenance. These deposits can also cause self-closing valves to stick.

High levels of iron and manganese do not pose any known adverse heath risks. The U.S. Environmental Protection Agency (EPA) has not set maximum contaminant levels (MCL) for iron and manganese in the National Primary Drinking Water Regulations. Secondary maximum contaminant levels (SMCL) recommended in the National Secondary Drinking Water Regulations are set for esthetic reasons and are not enforceable by EPA, but are intended as guides to the States. The SMCL for iron is 0.3 milligrams per liter (mg/L) and the SMCL for manganese is 0.05 mg/L. States may adopt SMCLs as guidelines or enforce them as contaminants. FSM 7400-Public Health and Pollution Control Facilities requires all Forest Service water systems to comply with the SMCLs.

Testing
Have water quality tests performed by an accredited lab prior to planning, designing, or contracting treatment for iron and or/manganese. The ability of various treatment techniques to remove iron and manganese are affected by pH, hardness, presence of iron bacteria, silica, sulfur, tannin, organic material, and the concentration and form of iron and manganese. Water quality tests report the concentration of iron and/or manganese, but not the form.

Iron and manganese in water may be in three forms. When water comes from the tap as clear, Fe/MN is in the dissolved form of ferrous iron (Fe2+) or manganous manganese (Mn2+). When the water comes from the tap as rust colored, Fe/Mn is in the precipitate form of ferric iron or manganic manganese. When the water comes from the tap with a clear yellow tint, the Fe/Mn has combined with organic matter and is called colloidal. Colloidal Fe/Mn is the most difficult to remove.

Iron bacteria may also be present in wells or grow in the distribution system. A rust-colored slime will form on fixtures and in pipes when iron bacteria are present. Iron bacteria should be controlled in the well to prevent fouling of well screens. Iron bacteria in the distribution system will cause an increase in chlorine demand. Periodic shock chlorination of the well and distribution system will control bacteria.

Treatment
Treatment options include sequestering, ion exchange, oxidizing filters, and oxidation and filtration or settling. The most appropriate and cost-effective option depends on the concentration and form of Fe/Mn, water chemistry, and how much water needs to be treated.

Sequestering
Sequestering does not remove Fe/Mn from the water. Sequestration binds the Fe/Mn in soluble form preventing the compound from oxidizing on contact with air or chlorine. This is only an option if the iron is in the form of ferrous iron (Fe2+), manganese as manganous (Mn2+), and if the combined concentration is less than 1 to 3 mg/L. Sequestering prevents staining of plumbing fixtures and discoloration of the water, but a slight metallic taste remains. Sequestering agents break down at high temperatures found in water heaters.

Polyphosphates followed by chlorination can be an inexpensive method for sequestering Fe/Mn. Polyphosphates can be added to the water as a dry feed crystal or as a liquid solution with a metering pump. Polyphosphates can be effective in a pH range of 5.0 to 8.0. Because phosphate compounds are nutrients that contribute to the eutrophication of surface waters, appropriate methods of treating the waste water must be used.

Sodium silicate and chlorine is effective to sequester iron, but is less effective for manganese. Sodium silicate does not break down as readily as phosphate compounds in hot water heaters.

Ion Exchange
Ion exchange, such as salt-based water softeners, can remove small amounts of soluble iron and/or manganese from water. Potassium chloride may be used to regenerate the resin beads instead of sodium chloride if the added sodium is of concern. Water softeners are usually only considered if water hardness is also a problem, however, they should be considered when the combined iron and manganese is less than 2 to 5 mg/L. At higher concentrations, precipitated iron residue may buildup on the softening resin, decreasing the efficiency of the softener. Washing the resin with an acid or sodium bisulfate is necessary to remove the residue.

Ion exchange will not work if the iron has oxidized, if the iron has combined with organic material or humic acid, or if iron bacteria is present.

Oxidizing Filters
Oxidizing filters can remove up to 15-25 mg/L of combined concentrations of Fe/Mn. Greensand, anthracite sand, natural or synthetic zeolites are used in a mixed media or a pressure filter. Potassium permanganate (KMnO4) is used to coat greensand and anthrasand with manganese oxide, giving it a catalytic effect. This coating oxidizes and removes Fe/Mn, usually without requiring an additional oxidation/precipitation step. The coating can be maintained either by a continuous potassium permanganate feed or by backwashing at set intervals with a potassium permanganate solution.

Natural and synthetic zeolite filter media have a catalytic effect that does not require chemical backwashing to remove the precipitate. The filter media may use venturi air injection as an oxidant, with an air relief valve that bleeds off excess air. The oxidation process is completed in the zeolite media filter, and the precipitate is filtered out. The filter is periodically backwashed to remove the precipitant.

Oxidizing filters can be used with ferrous or ferric iron, and manganous or manganic manganese. The minimum pH is 7.0. A pH of 8.0 is needed when the manganese concentration is high. Filtering over marble chips can raise the pH if needed. The rate of backwash is higher than for ion exchange, but unlike phosphate and sodium chloride potassium permanganate is not an environmental issue.

Tannins and hydrogen sulfides will foul the filter media, reducing efficiency. Oxidizing filters work best with water low in phosphate and organic material. Chlorine will adversely affect the catalytic property of the filter media, and should be added after filtration.

Oxidation and Filtration/Settling
Oxidation
Oxidation is required before precipitation, settling and/or filtration. Soluble ferrous iron (Fe2+) is oxidized to a ferric iron (Fe3+), which readily forms the insoluble iron hydroxide complex Fe(OH)3. Manganous (Mn2+) is oxidized to manganic (Mn4+), which forms insoluble manganese dioxide (MnO2). The insoluble metals can be precipitated out in a settling tank or removed by filtration.

Aeration can be an effective, low-cost method of oxidation of iron. Water is passed down a series of porous trays by gravity to provide contact between air and water. Air stripping towers can also provide aeration. The water trickles down through a tower packed with an open plastic media while air is forced up through the media. Aeration towers also remove sulfides, radon, and volatile organic chemicals (VOCs). Venturi nozzles can be used to introduce air into the water. Aeration will not be as effective if iron bacteria or humic materials are present. The rate of reaction for manganese is very slow at pH values less than 9.5.

Chlorine is commonly used as an oxidant. Chlorine feed rate and contact time can be determined by simple jar tests. Trihalomethanes (THMs) may be a problem if organic material (VOCs, humic materials, etc.) is present in the water. The water will need to be monitored for chlorine residual content in the distribution system. Certified water treatment operators are required when chlorine is added to drinking water.

Potassium permanganate (KMnO4) is a very efficient oxidant of both iron and manganese. It is more expensive than chlorine, but capital equipment costs are usually less. The dose of potassium permanganate must be carefully controlled. Too little will not oxidize all the iron and manganese, too much will leave a pink tinge in the water.


Settling/Filtration
A detention tank allows contact time for the oxidation process to occur. The size of the detention tank depends on flow rate, oxidation method, tank configuration, and other oxidizable contaminants in the water. A jar test or bench test can be useful to select an oxidation method and detention time. Fill a sample jar with water. Mix air or chemical oxidant with the water and let it stand. Record the time it takes for the water to turn a rusty color and the dose and type of oxidant added. Leave the sample undisturbed and record the time it takes for the rusty color to settle to the bottom of the jar; or pour the rust-colored water through a lab filter of known pore size.

Aeration oxidation followed by a settling tank is an inexpensive treatment option for small water systems that does not require chemical additions or frequent monitoring. It will not be effective in all cases and bench or jar tests must be done to determine the feasibility and cost of this method. Inclined plate settlers, tube settlers, or baffles can be used in the settling tank to provide the maximum detention time. Settling tanks must be designed to allow the precipitate to be removed periodically.


Filtration
Filtration is the most common method of removing iron and manganese after oxidation. Slow sand filters, bag or cartridge filters, pressure filters, or conventional filters can remove the oxidized contaminants. Slow sand filters and conventional filters are the most expensive alternatives and are not normally used for removing Fe/Mn unless colloidal particles, bacteria, or other filterable contaminants are present. Bag or cartridge filters have a very low capital cost, but higher maintenance cost in filter replacement. Automatically backwashing pressure filters have a higher capital cost and a lower maintenance cost.

Packaged, pre-engineered iron and manganese filters are available in any size. Most companies that pre-engineer Fe/Mn filters will test a sample of your water and recommend chemical dose, pretreatment requirements, size, and filter media type. Ensure that these systems or all components have been tested to NSF Standard 61 or equivalent for potable water or food grade use.

References
American Water Works Association Research Foundation
O.N.: 90558; Sequestering methods of iron and manganese treatment.
National Drinking Water Clearing House
"Iron and Manganese Removal" Tech Brief Nine,
September 1998

New Hampshire Department of Environmental Services
Technical Bulletin WD-WS-3-8.

University of Nebraska
NebGuide G96-12800-A' Drinking Water: Iron and Manganese.

Wisconsin Department of Natural Resources
"Iron in Drinking Water" WS-35.

Product Literature

Water testing, greensand filters, water softeners, design assistance
Culligan International Company Muncipal/Commercial Systems
One Culligan Parkway
Northbrook, IL 60062
Phone: 847-205-6000
FAX: 847-205-6030
Email: internationalinfo@culligan.com
URL: http://www.culligan.com/americas.asp

AWS Advanced Water Systems
743 41st Avenue
Santa Cruz, CA 95062
Phone: 831-476-0515
FAX: 831-476-0832
Email: info@advancedh2o.com
URL: http://www.advancedh2o.com

Engineered media filters, water softeners, design assistance
Kinetico, Inc.
10845 Kinsman Road
Newbury, OH 44065
Phone: 440-564-9111
FAX: 440-564-9541
Toll Free: 800-321-5022
Email: commercial@kinetico.com
URL: http://www.kinetico.com

Electromedia® filters, complete treatment packages from 10 gpm and up, design assistance
Filtronics, Incorporated
4000 Leaverton Court
Anaheim, CA 92801-1610
Phone: 714-630-5040
FAX: 714-630-1160
Email: info@filtronics.com
URL: http://www.filtronics.com

Polyphosphates, crystal, powder, or liquid
The Kjell Corporation (Now owned by Carus Chemical Company)
315 Fifth Street
Peru, IL 61354
FAX: 815-223-4486
Toll Free: 800-435-6856
URL: http://www.caruschem.com

Potassium permanganate
Carus Chemical Company
315 Fifth Street
Peru, IL 61354
FAX: 815-223-4486
Toll Free: 800-435-6856
URL: http://www.caruschem.com

Additional sources available from:
American Water Works Association-Advertiser
(http://www.awwa.org)

Thomas Register-Online
(http://www.thomasregister.com)

NSF International
(http://www.nsf.org)


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For Additional Information Contact:
Engineering Program Leader
San Dimas Technology and Development Center
444 East Bonita Avenue, San Dimas CA 91773-3198
Phone 909-599-1267; TDD: 909-599-2357; FAX: 909-592-2309
E-mail: mailroom_wo_sdtdc@fs.fed.us

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